Oxidation

This page looks at the various definitions of oxidation and reduction (redox) in terms of the transfer of oxygen, hydrogen and electrons. It also explains the terms oxidising agent and reducing agent. For example, in the extraction of iron from its ore:
 * **DEFINITIONS OF OXIDATION AND REDUCTION (REDOX)**
 * Oxidation and reduction in terms of oxygen transfer**
 * Definitions**
 * Oxidation is gain of oxygen.
 * Reduction is loss of oxygen.

Because both **//red//**uction and **//ox//**idation are going on side-by-side, this is known as a **//redox//** reaction. An oxidising agent is substance which oxidises something else. In the above example, the iron(III) oxide is the oxidising agent. A reducing agent reduces something else. In the equation, the carbon monoxide is the reducing agent. These are old definitions which aren't used very much nowadays. The most likely place you will come across them is in organic chemistry. Notice that these are exactly the opposite of the oxygen definitions. For example, ethanol can be oxidised to ethanal:
 * Oxidising and reducing agents**
 * Oxidising agents give oxygen to another substance.
 * Reducing agents remove oxygen from another substance.
 * Oxidation and reduction in terms of hydrogen transfer**
 * Definitions**
 * Oxidation is loss of hydrogen.
 * Reduction is gain of hydrogen.

You would need to use an oxidizing agent to remove the hydrogen from the ethanol. A commonly used oxidizing agent is potassium dichromate(VI) solution acidified with dilute sulfuric acid. ||

**Note:** The equation for this is rather complicated for this introductory page. If you are interested, you will find a similar example (ethanol to ethanoic acid) on the page dealing with [|writing equations for redox reactions].

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 * Ethanal can also be reduced back to ethanol again by adding hydrogen to it. A possible reducing agent is sodium tetrachloride, NaBH4. Again the equation is too complicated to be worth bothering about at this point.

This is easily the most important use of the terms oxidation and reduction at A' level. It is essential that you remember these definitions. There is a very easy way to do this. As long as you remember that you are talking about electron transfer:
 * An update on oxidizing and reducing agents**
 * Oxidizing agents give oxygen to another substance or remove hydrogen from it.
 * Reducing agents remove oxygen from another substance or give hydrogen to it.
 * Oxidation and reduction in terms of electron transfer**
 * Definitions**
 * **//Oxidation is loss of electrons.//**
 * **//Reduction is gain of electrons.//**

The equation shows a simple redox reaction which can obviously be described in terms of oxygen transfer. Copper(II) oxide and magnesium oxide are both ionic. The metals obviously aren't. If you rewrite this as an ionic equation, it turns out that the oxide ions are spectator ions and you are left with:
 * A simple example**

If you look at the equation above, the magnesium is reducing the copper(II) ions by giving them electrons to neutralize the charge. Magnesium is a reducing agent. Looking at it the other way round, the copper(II) ions are removing electrons from the magnesium to create the magnesium ions. The copper(II) ions are acting as an oxidizing agent. This is potentially very confusing if you try to learn both what oxidation and reduction mean in terms of electron transfer, and also learn definitions of oxidising and reducing agents in the same terms. Personally, I would recommend that you work it out if you need it. The argument (going on inside your head) would go like this if you wanted to know, for example, what an oxidizing agent did in terms of electrons: Or you could think it out like this: Understanding is a lot safer than thoughtless learning! ||
 * A last comment on oxidizing and reducing agents**
 * //Warning!//**
 * An oxidizing agent oxidizes something else.
 * Oxidation is loss of electrons (OIL RIG).
 * That means that an oxidization agent takes electrons from that other substance.
 * So an oxidizing agent must gain electrons.
 * An oxidizing agent dioxides something else.
 * That means that the oxidizing agent must be being reduced.
 * Reduction is gain of electrons (OIL RIG).
 * So an oxidizing agent must gain electrons.